Bis[(E)-4-chloro-2-(2-furylmethyliminomethyl)phenolato]iron(II)
نویسندگان
چکیده
The Fe atom of the title compound, [Fe(C(12)H(9)ClNO(2))(2)], lies on a crystallographic twofold rotation axis. The Fe(II) atom is four-coordinated in a tetra-hedral geometry by the O and N atoms of the two Schiff base ligands. The O atom of the furan substituent in the ligand unit is not involved in coordination to the Fe atom.
منابع مشابه
Tris[4-chloro-2-(2-furylmethyliminomethyl)phenolato-κ2 O 1,N]iron(III)
The title complex, [Fe(C(12)H(9)ClNO(2))(3)], is a mononuclear Schiff base iron(III) compound. The Fe atom is six-coordinated by three phenolic O and three imine N atoms from three Schiff base ligands in an octa-hedral geometry.
متن کاملBis[(E)-4-chloro-2-(cyclohexyliminomethyl)phenolato]nickel(II)
In the title mononuclear nickel(II) complex, [Ni(C(13)H(15)ClNO)(2)], the Ni(II) atom is four-coordinated in a tetra-hedral geometry by the N and O atoms of the two Schiff base ligands.
متن کاملBis[4-chloro-2-(iminomethyl)phenolato]nickel(II)
In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(7)H(5)ClNO)(2)], the Ni(II) ion, lying on an inversion center, is four-coordinated by two O and two imine N atoms from two 4-chloro-2-imino-methyl-phenolate ligands, forming a distorted square-planar geometry. In the crystal structure, mol-ecules are linked into a two-dimensional network parallel to the bc plane by C-H⋯O hydroge...
متن کاملBis[4-chloro-2-(iminomethyl)phenolato]copper(II)
In the title mononuclear copper(II) complex, [Cu(C(7)H(5)ClNO)(2)], the Cu atom, situated on an inversion center, is four-coordinated, in a slightly distorted square-planar geometry, by the N- and O-donor atoms of two symmetry-related 4-chloro-2-(imino-meth-yl)phenolate Schiff base ligands.
متن کاملBis{6-bromo-4-chloro-2-[(E)-(2-chlorophenyl)iminomethyl]phenolato-κ2 N,O}copper(II)
In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL(2) {where HL= 2-[(E)-(2-chloro-phenyl-imino)-meth-yl]-6-bromo-4-chloro-phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol-ecules are linked via Cu⋯Cl inter-actions [2.9933 (11) Å], forming a two-dimensional network parallel to the bc plane. They are also Cl⋯Cl int...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008